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This contribution explores the interaction of the fibrous silicates, palygorskite, sepiolite and chrysotile with a wide range of organic agents. Infrared spectroscopy (IR) methods are essential for th...
Abstract: Amorphous derivates prepared by aqueous reaction of various aluminosilicate clay minerals with concentrated KF solution at 80–110°C were studied for their gas adsorption properties. The four...
A new, well-ordered, thermally robust ethylene glycol intercalate of kaolinite was formed by refluxing the dimethyl sulfoxide intercalate of kaolinite (Kao-DMSO) with dry ethylene glycol (EG). This ne...
Abstract: Kaolinite: alkali halide intercalates have been successfully prepared by grinding the salt with kaolinite in the absence of water. Rate of intercalation is shown to correlate negatively with...
Kaolinite:NaCl intercalates with basal layer dimensions of 0.95 and 1.25 nm have been prepared by direct reaction of saturated aqueous NaCl solution with well-crystallized source clay KGa-1. The inter...
The reaction of gibbsite in various organic solvents at 250°–300°C under spontaneous vapor pressure of the solvents was examined. Glycols and aminoalcohols afforded the organic derivatives of boehmite...
Abstract: Stable organomineral derivatives are formed by reaction of organochlorosilanes with certain phyllosilicates. Organosiloxyl functions are grafted on silanol groups present at external mineral...
Highly significant differences are observed between the methyl derivatives of attapulgite, produced when this mineral is reacted with (CH3)2Si(OC2H5)2, in the presence or in absence of HCl. In the fir...
Highly significant differences are observed between the methyl derivatives of attapulgite,produced when this mineral is reacted with (CHz)zSi(OCzHs)2, in the presence or in absence of HCI. In the firs...
Sorption of aniline and its derivatives by montmorillonite substituted by cations of widely different acidity depends upon the polarizing power of the interlayer cations. Infra-red spectra indicate th...

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