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Abstract: Partial stabilization of Fe(II) in chemically reduced smectite, which normally readily undergoes reoxidation in air, was achieved. The purpose of this study was to determine if Fe(II) can be...
Abstract: Hydroxyaluminosilicate (HAS) and hydroxyaluminum (HyA) ionic solutions having final Al concentrations ranging from 3.74 to 4.00 mM; NaOH/Al molar ratios of 1.0, 2.0 and 2.5; and Si/Al molar ...
During an electron microscope study of the weathering of granite from southern New South Wales, Australia, an assemblage of minerals including florencite and rhabdophane was discovered replacing apati...
The amount of K fixed in K- and Ca-saturated montmorillonite, vermiculite (trioctahedral), rectorite-type and IMII-ordered mica/montmorillonites was measured as a function of time (1–64 days), tempera...
Two variables must be considered when calculating exchange free energies (ΔG0ex) for 2:1 clays: (1) anionic field strength, as expressed by equivalent anionic radius (ra), and (2) interlayer water con...
The effects of hydrothermal conditions on the sorption and fixation of cesium by various clay minerals and shales were investigated. Hydrothermal heating, which may be expected in a radioactive waste ...
Investigations concerning selective sorption and fixation of K and similar cations by clay minerals and soil clays and the mechanisms of these reactions are reviewed. In particular, recent observation...
The rates of K exchange of untreated and peroxide-treated micaceous clays from five Podzol soils of increasing degrees of weathering were determined using sodium tetraphenyl boron. In addition, the am...
Soil vermiculite clays of varying tetrahedral and octahedral composition and cation exchange capacity (CEC) were examined for their ability to fix K+ in both the wet and dry states. Fixation capacity,...
Boron Fixation by Illites     Boron Fixation  Illites       2012/2/21
The mechanism of boron uptake by clays, especially illitic clays, and the factors which control such uptake have long been debated issues. In an attempt to answer some of the questions of the controve...

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