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Slow, ~50 ps, P* → P(+)HA(-) electron transfer is observed in Rhodobacter capsulatus reaction centers (RCs) bearing the native Tyr residue at M208 and the single amino acid change of isoleucine at M20...
The short-lived (<1 ps) initial intermediate state P(+)B(L)(-) in the photoinduced charge separation process of the bacterial photosynthetic reaction center has been trapped in two D(LL)-based Rhodoba...
Stark spectra have been obtained in the region of absorption by the accessory bacteriochlorophylls (the B-band region around 800 nm) in Rhodobacter sphaeroides reaction centers. The Stark spectra in t...
In bacterial photosynthetic reaction centers, ultrafast singlet excited-state energy transfer occurs from the monomeric bacteriochlorophylls, B, and bacteriopheophytins, H, to the homodimer special pa...
The Stark spectrum of the intervalence band of the special pair radical cation in bacterial photosynthetic reaction centers is presented. This spectrum, centered at 2600 cm-1, is modeled using a gener...
Ultrafast singlet excited state energy transfer occurs from the monomeric bacteriopheophytin (H) and bacteriochlorophyll (B) chromophores to the primary electron donor or special pair (P) in bacterial...
Higher order Stark spectroscopy has recently been introduced and applied to characterize the electrooptic properties of chromophores in bacterial photosynthetic reaction centers.1 In the course of the...
The magnitudes of inter-chromophore interactions in bacterial photosynthetic reaction centers are investigated by measuring absorption and Stark spectra of reaction centers in which monomeric chromoph...
The electronic absorption spectrum of the homodimeric special pair in bacterial photosynthetic reaction centers is greatly modified when one of the bacteriochlorophylls is replaced by a bacteriopheoph...
Ultrafast singlet excited state energy transfer occurs from the monomeric chromophores to the primary electron donor or special pair in photosynthetic reaction centers. The mechanism of this process h...
Resonance Raman spectra and absolute Raman scattering intensities of the Franck-Condon coupled vibrational modes of the accessory bacteriochloropyhlls (B) in the photosynthetic reaction center from Rb...
The spontaneous fluorescence from the special pair primary electron donor in bacterial photosynthetic reaction centers has been measured at low temperature using fluorescence up-conversion following e...
Rapid-flow resonance Raman spectra of the primary electron donor (a bacteriochlorophyll dimer known as P) and of the monomeric accessory bacteriochlorophylls (B) in the bacterial photosynthetic reacti...
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
Extremely long distance electron transfer is observed in some photosynthetic reaction centers. For several charge recombination reactions, the rate appears to fall off much more slowly with distance t...

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